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21.
Narcis Ghisovan Abdellatif Nemri Svetlana Shumikhina Stephane Molotchnikoff 《BMC neuroscience》2008,9(1):60
Background
Visual neurons respond essentially to luminance variations occurring within their receptive fields. In primary visual cortex, each neuron is a filter for stimulus features such as orientation, motion direction and velocity, with the appropriate combination of features eliciting maximal firing rate. Temporal correlation of spike trains was proposed as a potential code for linking the neuronal responses evoked by various features of a same object. In the present study, synchrony strength was measured between cells following an adaptation protocol (prolonged exposure to a non-preferred stimulus) which induce plasticity of neurons' orientation preference. 相似文献22.
[reaction: see text] Enantioselective Ir-catalyzed intramolecular allylic aminations and etherifications are described. Up to 97% ee was achieved using catalysts prepared by in situ activation of mixtures of phosphorus amidites and [Ir(COD)Cl]2. Sequential aminations of bis-allylic carbonates, involving an inter- followed by an intramolecular reaction, gave trans-N-benzyl-2,5-divinylpyrrolidine and trans-N-benzyl-2,6-divinylpiperidine with > or = 99% ee. New phosphorus amidites as well as improved conditions for intermolecular aminations are reported. 相似文献
23.
It is shown that, when a Monte Carlo algorithm is used for estimation of any physical quantity A, a simple and fast additional procedure can be implemented that simultaneously estimates the sensitivity of A to any problem parameter. The proposed approach is general and systematic in the sense that: (i) it includes domain-deformation sensitivities, i.e., cases where a change in the parameter modifies the domain over which the sampled random variables are defined and (ii) a simple generic procedure is presented to address all remaining free choices in terms of variance minimization. 相似文献
24.
G. Benzoni F. Azaiez S. Leoni S. Battacharyya R. Borcea A. Bracco L. Corradi D. Curien G. De France Zs. Dombrádi E. Fioretto S. Franchoo S. Grevy F. Ibrahim S. Iulian G. Mukherjee A. Navin G. Pollarolo N. Redon P. H. Regan M. Rejmund C. Schmitt G. Sletten D. Sohler M. Stanoiu S. Szilner D. Verney 《The European physical journal. Special topics》2007,150(1):83-86
A study of deep-inelastic and multi-nucleon transfer reactions to populate neutron-rich
O, Ne and F nuclei is here presented. The reaction under analysis employed a beam of radioactive
24Ne at 7.9 AMeV, provided by the
SPIRAL facility at Ganil, impingin on a 208Pb target. The reaction products have been
detected in the VAMOS spectrometer in coincidence with gamma rays
measured by the EXOGAM array. Preliminary results here presented show a selectivity
in the population of states of different nature. 相似文献
25.
The different rheological behaviour of natural rubber (NR) compared to industrial synthetic poly(cis-1,4-isoprene) (SR) has been attributed to the gel phase and long-chain branching. Previous studies on branching in NR were carried out using the fractionation technique by precipitation to obtain narrow molar mass distribution. In this study, chain branching of poly(cis-1,4-isoprene) in NR was characterised by size-exclusion chromatography coupled with an online multi-angle light scattering detector (SEC-MALS). The nanoaggregates adsorbed on the column packing interfered with branching characterisation for short and medium chains (Mw < 1000 kg/mol). Using a master curve of linear standard poly(cis-1,4-isoprenes), SEC-MALS revealed no or very little branching in the higher chains (1000 < Mw < 10,000 kg/mol) of natural rubber contrary to previous studies. This study showed that the soluble portion of NR samples was composed of almost linear poly(cis-1,4-isoprene) and nanoaggregates with rather compact structures. 相似文献
26.
Eva Raluy Oscar Pàmies Montserrat Diéguez Stephane Rosset Alexander Alexakis 《Tetrahedron: Asymmetry》2009,20(16):1930-1935
A sugar-based phosphite–phosphoroamidite and diphosphoroamidite ligand library L1–L5a–g was tested in the asymmetric Cu-catalyzed 1,4-conjugate addition reactions of β-substituted and β,β′-disubstituted enones. Our results indicated that the selectivity was strongly dependent on the ligand parameters and on the substrate structure. Moderate-to-good enantioselectivities (ees up to 84%) were obtained in the 1,4-addition of several types of β-substituted cyclic and linear substrates. Of particular note is the high enantioselectivity (ees up to 90%) obtained for the more challenging β,β′-disubstituted 3-methyl-cyclohexenone. 相似文献
27.
28.
M. -G. Porquet Ts. Venkova A. Astier I. Deloncle A. Prévost F. Azaiez A. Buta D. Curien O. Dorvaux G. Duchêne B. J. P. Gall F. Khalfallah I. Piqueras M. Rousseau M. Meyer N. Redon O. Stézowski R. Lucas A. Bogachev 《The European Physical Journal A - Hadrons and Nuclei》2006,28(2):153-159
The 87Kr nucleus has been produced as fission fragment in the fusion reaction 18O + 208Pb at 85MeV bombarding energy and studied with the Euroball IV array. High-spin states of this neutron-rich isotope have been
identified for the first time. Its level scheme has been obtained up to 6.3MeV excitation energy and spin I ∼ 23/2ℏ. Its structure is interpreted by analogy with those of the heavier isotones. The proposed configurations involve
both proton and neutron excitations from several sub-shells located close to the Fermi levels, particularly νd5/2, πp3/2f5/2 and πg9/2. Moreover, a revised spin value of 5/2- for the 87Br ground state is proposed. 相似文献
29.
Yi-Bin Ruan Stephane Maisonneuve Chun Li Jie Tang Juan Xie 《Frontiers of Chemistry in China》2010,5(2):208-213
Fluoroionophoric properties of benzothiadiazoyl-bistriazoyl amino acids derivatives toward metal ions were investigated by
UV-Vis and fluorescence spectroscopy. Our results show that the watersoluble lysine derivative 2 exhibited a significant selectivity
toward Cu2+ in “on-off” type response in buffer solution at pH 7.4. 相似文献
30.